To apply, pour the vinegar straight into a spray bottle, and thoroughly mist the weed to be removed (figure A). In about one week, especially during 90-degree weather, the weed dries up (figure B). (In cooler climates such as the Pacific Northwest, however, vinegar doesn't work nearly as well.) Vinegar strips the waxy protective coating from the plant surfaces, causing the leaves to dry out and often desiccating the plant all the way down to the roots. James recommends spraying the weeds two to three times a day at 5- to 10-day intervals.This all-natural weed treatment is not without some problems, though. One thing to remember about vinegar is that it's non-selective, meaning that it destroys anything green, whether weeds or a prized plant. Take extra care when using it, and avoid vinegar treatments altogether on windy days.
Another problem is that regular store-bought vinegar, which contains only 5 percent vinegar or acetic acid, isn't strong enough to deal with persistent problem weeds. However, you can now buy vinegar that is especially developed for use as an herbicide, and it contains 20 percent acetic acid, four times stronger than the kitchen variety. Garden vinegar does a much better job of eliminating tough, nasty weeds.
Also, too much vinegar can have an adverse affect on the soil's pH level. "After all, vinegar is pretty acidic," explains James, "so I suggest you use it only to spot treat weedy areas in flower beds rather than in or on the lawn, and don't over-do it when spraying." Treating a large area of lawn soaks the soil with too much vinegar, resulting in an overall decrease of the pH level. "Actually, some people do douse the soil with this stuff to lower the pH to the point where few if any plants will grow," says James, "but I dont recommend it for that use because it renders the soil inhospitable to plants for at least six months."